Collective Interatomic Decay of Multiple Vacancies in Clusters

We predict that inner-shell ionization of more than one atom (or molecule) in a cluster, e.g., by intense free-electron laser radiation, can lead to an interatomic decay process in which the formed vacancy states decay simultaneously, while a neighboring neutral species is ionized. This collective decay phenomenon can be regarded as a transfer of two or more virtual photons from the ionized cluster units to a neutral one. Simulations of collective decay in (4(s)(-1), 4(s)(-1)) (Kr(+))(2)Ar show that the two-virtual-photon process can be competitive with the dissociative nuclear dynamics of the doubly ionized cluster. Generality of the collective interatomic decay is discussed.