期刊
PHYSICAL REVIEW LETTERS
卷 100, 期 11, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.100.115503
关键词
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Most chemical reactions require activation which is conventionally supplied by heat. In stark contrast, mechanical activation by applied external forces opens intriguing novel possibilities. Here, the first direct comparison of mechanical versus thermal activation of bond breaking is provided. Studying both thiolate-copper interfaces and junctions provides evidence for vastly different reaction pathways and product classes. This is understood in terms of directional mechanical manipulation of coordination numbers and system fluctuations in the process of mechanical activation.
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