期刊
PHYSICAL REVIEW LETTERS
卷 101, 期 18, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.101.184501
关键词
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A novel phase-field model is developed for the quantitative modeling of the complex electrochemical-hydrodynamic interactions in narrow fluidic confinements. Through an order parameter variation, this model captures the underlying excluded volume effects, solvation interactions, and preferential polarizabilities in a self-consistent fashion, without resorting to computationally prohibitive molecular dynamics simulations. Agreement with molecular dynamics predictions is found to be quantitative.
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