4.7 Article

Intermolecular Casimir-Polder forces in water and near surfaces

期刊

PHYSICAL REVIEW E
卷 90, 期 3, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.90.032122

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资金

  1. European Commission
  2. Research Council of Norway [221469]
  3. Swedish Research Council [90499401]
  4. Department of Energy and Process Engineering (NTNU, Norway)
  5. Australian Commonwealth Government

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The Casimir-Polder force is an important long-range interaction involved in adsorption and desorption of molecules in fluids. We explore Casimir-Polder interactions between methane molecules in water, and between a molecule in water near SiO2 and hexane surfaces. Inclusion of the finite molecular size in the expression for the Casimir-Polder energy leads to estimates of the dispersion contribution to the binding energies between molecules and between one molecule and a planar surface.

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