期刊
PHYSICAL REVIEW E
卷 82, 期 5, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.82.050401
关键词
-
资金
- NSF [EEC-0647560, DMR-0907781]
- NSEC, Northwestern University [EEC-0647560]
Simple expressions are presented for the equations of state of a correlated electrolyte solution, calculated straightforwardly within a full nonlinear Debye-Huckel approach in terms of the mean potential at contact, that predict quantitatively different phase behavior from the popular Debye-Huckel limiting law. The theory includes pair correlations accurately and may provide a basis for a quantitative theoretical study of organic or multivalent ionic solutions. As an example, cohesive effects are addressed of strong couplings between ions on the effective interactions between nanoparticles.
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