期刊
PHYSICAL REVIEW B
卷 88, 期 17, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.88.174102
关键词
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资金
- National Science Foundation [DMR 1006772]
- NSF [DMR 1004804]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1359523, 1004804] Funding Source: National Science Foundation
A charge compensation mechanism is proposed for cation vacancy defects in complex oxides based on positron lifetime measurements, infrared spectroscopy, and composition analysis. Defects were characterized in samples of yttrium aluminum garnet grown in O-2 or Ar. However, no positron trapping was detected in samples grown in H-2. This is attributed to decoration of cation vacancies with hydrogen, thereby passivating charges of vacancies that otherwise function as positron traps. Infrared spectroscopy gave direct evidence of the presence of hydrogen. Passivation of cation vacancies with hydrogen is proposed as an important mechanism for charge compensation in the defect physics of oxides.
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