期刊
PHYSICAL REVIEW B
卷 79, 期 11, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.79.113201
关键词
EPR spectroscopy; ferromagnetic materials; ion beam effects; magnetic moments; Raman spectra; titanium compounds; vacancies (crystal); X-ray diffraction
资金
- Bundesministerium fur Bildung und Forschung [FKZ03N8708]
In this Brief Report we show that ferromagnetism can be induced in pure TiO2 single crystals by oxygen ion irradiation. By combining x-ray diffraction, Raman scattering, and electron-spin resonance spectroscopy, a defect complex, i.e., Ti3+ ions on the substitutional sites accompanied by oxygen vacancies, has been identified in irradiated TiO2. This kind of defect complex results in a local (TiO6-x) stretching Raman mode. We elucidate that Ti3+ ions with one unpaired 3d electron provide the local magnetic moments.
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