4.6 Article

Ergodicity breaking in strong and network-forming glassy systems

期刊

PHYSICAL REVIEW B
卷 79, 期 17, 页码 -

出版社

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.79.172201

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germanate glasses; glass transition; neutron diffraction; statistical mechanics; vitreous state

资金

  1. ILL
  2. European Commission [Rll3-CT-2003-505925]

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The temperature dependence of the nonergodicity factor of vitreous GeO2, f(q)(T), as deduced from elastic and quasielastic neutron scattering experiments, is analyzed. The data are collected in a wide range of temperatures from the glassy phase, up to the glass-transition temperature, and well into the undercooled liquid state. Notwithstanding the investigated system is classified as prototype of strong glass, it is found that the temperature and the q behavior of f(q)(T) follow some of the predictions of mode coupling theory. The experimental data support the hypothesis of the existence of an ergodic to nonergodic transition also in network-forming glassy systems.

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