4.6 Article

Large-J approach to strongly coupled spin-orbital systems

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PHYSICAL REVIEW B
卷 80, 期 18, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.80.180409

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angular momentum; exchange interactions (electron); ground states; localised states; spin-orbit interactions; strontium compounds

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We present an approach to study the ground-state and elementary excitations in compounds where spins and orbitals are entangled by on-site relativistic spin-orbit interaction. The appropriate degrees of freedom are localized states with an effective angular momentum J. We generalize J to arbitrary large values while maintaining the delicate spin-orbital entanglement. After projecting the intersite exchange interaction to the manifold of effective spins, a systematic 1/J expansion of the effective Hamiltonian is realized using the Holstein-Primakoff transformation. Applications to representative compounds Sr2IrO4 and particularly vanadium spinels AV(2)O(4) are discussed.

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