4.6 Article

Exciton diffusion in energetically disordered organic materials

期刊

PHYSICAL REVIEW B
卷 80, 期 19, 页码 -

出版社

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.80.195209

关键词

diffusion; excitons; Monte Carlo methods

资金

  1. European Commission STREP [NMP-CT2006- 016434]
  2. Belgian Science Policy [P6/27]
  3. Belgian Research Science Foundation (FNRS and FRFC through the Interuniversity Scientific Calculation Facility, ISCF)

向作者/读者索取更多资源

We implement a simple, continuous, analytical model for exciton hopping in an energetically disordered molecular landscape. The model is parameterized against atomistic and lattice Monte Carlo simulations based on quantum-chemical calculations. It captures the essential physics of exciton diffusion in disordered media at different temperatures and yields a universal scaling law of the diffusion length with the dimensionless disorder parameter given by the ratio of the energetic disorder width to the thermal energy.

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