High-precision measurements of the diamond Hugoniot in and above the melt region

High-precision measurements of the diamond principal Hugoniot have been made at pressures between 6 and 19 Mbar. Shock velocities were determined with 0.3%-1.1% precision using a velocity interferometer. Impedance-matching analysis, incorporating systematic uncertainties in the equation of state of the quartz standard, was used to determine the Hugoniot with 1.2%-2.7% precision in density. The results are in good agreement with published ab initio calculations, which predict a small negative melt slope along the Hugoniot, but disagree with previous laser-driven shock wave experiments, which had observed a large density increase in the melt region. In the extensive solid-liquid coexistence regime between 6 and 10 Mbar, the present measurements indicate that the mixed phase is a few percent more dense than what would be expected from a simple interpolation between liquid and solid Hugoniots.