We present spectacular evidence of metallization of amorphous Ge films under high pressure using optical micrographs and Raman-scattering and x-ray-absorption spectroscopies. This transformation is identified as a low-density amorphous (LDA) to high-density amorphous (HDA) transition, relevant to a large class of systems including amorphous ice, semiconductors, and oxides. We have discovered that this transition initiates at the surface of the LDA sample, characterized intrinsically by a thickness dependent density of voids. Contrary to the case of transitions involving stable crystalline solid phases, our observations show that pressure-induced phase transitions in inhomogeneous amorphous samples are morphology driven and are favored for lower defect (void) densities. The metal disordered phase is observed first at 8 GPa for a lower density of voids, transforming to a metastable ordered phase upon depressurization. The local HDA structure is characterized by an increase in the first-neighbor coordination number, average distance, and variance.
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