期刊
PHYSICAL REVIEW B
卷 78, 期 13, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.78.134112
关键词
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资金
- European Node of Excellence [NOE MAGMANet 515767-2]
- European FLASH [MRTN-CT-2003503641]
- National Research Agency [NT05-3-45333]
- French ministry
- Region Bretagne (PRIR Femtocom 2178, SIE MagBreiz 2142, and Ph. D funding for J.H.)
Out-of-equilibrium photoinduced switching from the low-spin to the high-spin state has been investigated on the iron(II) complex [Fe-(II)(DPEA)(NCS)(2)] by both optical reflectivity and magnetic measurements under continuous light irradiation at low temperature. The photoinduced HS state can be observed up to 47 K and the relaxation process has been followed. Structural changes of both the temperature- and the photoinduced spin-state switching have been analyzed in detail by x-ray diffraction indicating no change of symmetry. Short intermolecular contacts and intramolecular deformations associated with the change of molecular spin state have been quantified. Actually a crossover behavior is observed at thermal equilibrium with however a quasiabrupt shape indicating significant cooperative effects. These aspects are compared between the temperature- and photoinduced spin crossovers.
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