Husimi distribution and phase-space analysis of a vibron-model quantum phase transition

The Husimi distribution is proposed for a phase-space analysis of quantum phase transitions in the two-dimensional U(3) vibron model for N-size molecules. We show that the inverse participation ratio and Wehrl's entropy of the Husimi distribution give sharp signatures of the quantum (shape) phase transition from linear to bent. Numerical results are complemented with a variational approach using parity-symmetry-adapted U(3) coherent states, which reach the minimum Wehrl entropy N(3+2N)/(N+1)(N+2), in the rigidly linear phase, according to a generalized Wehrl-Lieb conjecture. We also propose a characterization of the vibron-model quantum phase transition by means of the zeros of the Husimi distribution.