4.6 Article

Cold and ultracold NH-NH collisions in magnetic fields

期刊

PHYSICAL REVIEW A
卷 83, 期 2, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.83.022713

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  1. EPSRC
  2. Council for Chemical Sciences of the Netherlands Organization for Scientific Research (CW-NWO)
  3. EPSRC [EP/E039200/1, EP/I012044/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/E039200/1, EP/I012044/1] Funding Source: researchfish

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Elastic and spin-changing inelastic collision cross sections are presented for cold and ultracold magnetically trapped NH. The cross sections are obtained from coupled-channel scattering calculations as a function of energy and magnetic field. We specifically investigate the influence of the intramolecular spin-spin, spin-rotation, and intermolecular magnetic dipole coupling on the collision dynamics. It is shown that (NH)-N-15 is a very suitable candidate for evaporative cooling experiments. The dominant trap-loss mechanism in the ultracold regime originates from the intermolecular dipolar coupling term. At higher energies and fields, intramolecular spin-spin coupling becomes increasingly important. Our qualitative results and conclusions are fairly independent of the exact form of the potential and of the size of the channel basis set.

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