期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 16, 期 39, 页码 21144-21152出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp01701c
关键词
-
资金
- NERC
- CrystalMaker Software Ltd.
- EPSRC [EP/F067496]
- UoE HPCx Ltd at the University of Edinburgh
- Cray Inc
- NAG Ltd
- Office of Science and Technology through EPSRC
- EPSRC [EP/F067496/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F067496/1] Funding Source: researchfish
The mechanism of negative thermal expansion (NTE) in MOF-5 has been studied using a rigid unit mode analysis of the phonons responsible for NTE. In addition to confirming the role of the previously proposed optic 'trampoline mode' mechanism [Lock et al., Dalton Trans., 2013, 42, 1933-2320], we have identified a new acoustic mode mechanism that makes a major contribution to the macroscopic NTE of this framework.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据