期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 16, 期 10, 页码 4439-4455出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp54767a
关键词
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资金
- NSF [CHE-0718219, CHE-1150660]
- Direct For Mathematical & Physical Scien [1150660] Funding Source: National Science Foundation
- Division Of Chemistry [1150660] Funding Source: National Science Foundation
The light activated ring-opening reaction of the 1,3-cyclohexadiene chromophore finds application in optical control, optical switching, optical memory, light activated molecular machines, photobiology, photochromic materials, and conformation-specific photocatalysts. The development of ultrafast spectroscopic methods and powerful computational methods have accelerated the understanding and facilitated the application of this important chromophore in a wide range of systems. Here we look at the current state of theoretical and experimental understanding for the ring-opening reaction of the isolated cyclohexadiene molecule and the ring-opening reactions of substituted cyclohexadienes, including fulgides, diarylethenes, and provitamin D.
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