期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 16, 期 19, 页码 8761-8772出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp00461b
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资金
- Advanced Low Carbon Technology Research and Development Program (ALCA) of the Japan Science and Technology Agency (JST)
- Technology Research Grant Program of the New Energy and Industrial Technology Development Organization (NEDO) of Japan
Certain concentrated mixtures of salts and solvents are not simply solutions'' anymore, but they may be described as ionic liquids''. In this perspective paper, we describe possible criteria for the new family of ionic liquids: solvate'' ionic liquids. This subclass of ionic liquids was originally proposed by Angell et al. in their recent review; however, their criteria remain to be debated. Concentrated mixtures of lithium salts and organic solvents are useful models for these solvate ionic liquids, and the effects of the salt concentration, types of solvents, and counter anions of the lithium salts on their structure and properties have been explored to enable contrast with traditional solutions, and to help determine whether a given mixture belongs to the solvate ionic liquid or not.
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