4.6 Article

An assessment of vapour pressure estimation methods

期刊

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 16, 期 36, 页码 19453-19469

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp00857j

关键词

-

资金

  1. The Natural Environment Research Council [NE/J02175X/1, NE/J009202/1, NE/H002588/1]
  2. NERC [NE/H002588/1, NE/J009202/1, NE/J02175X/1, NE/I020121/1] Funding Source: UKRI
  3. Natural Environment Research Council [NE/J009202/1, 1231603, NE/I020121/1, NE/H002588/1, NE/J02175X/1] Funding Source: researchfish

向作者/读者索取更多资源

Laboratory measurements of vapour pressures for atmospherically relevant compounds were collated and used to assess the accuracy of vapour pressure estimates generated by seven estimation methods and impacts on predicted secondary organic aerosol. Of the vapour pressure estimation methods that were applicable to all the test set compounds, the Lee-Kesler [Reid et al., The Properties of Gases and Liquids, 1987] method showed the lowest mean absolute error and the Nannoolal et al. [Nannoonal et al., Fluid Phase Equilib., 2008, 269, 117-133] method showed the lowest mean bias error (when both used normal boiling points estimated using the Nannoolal et al. [Nannoolal et al., Fluid Phase Equilib., 2004, 226, 45-63] method). The effect of varying vapour pressure estimation methods on secondary organic aerosol (SOA) mass loading and composition was investigated using an absorptive partitioning equilibrium model. The Myrdal and Yalkowsky [Myrdal and Yalkowsky, Ind. Eng. Chem. Res., 1997, 36, 2494-2499] vapour pressure estimation method using the Nannoolal et al. [Nannoolal et al., Fluid Phase Equilib., 2004, 226, 45-63] normal boiling point gave the most accurate estimation of SOA loading despite not being the most accurate for vapour pressures alone.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据