期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 16, 期 6, 页码 2285-2288出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp53953a
关键词
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资金
- French-Croatian project Cogito, MZOS [098-0352851-2921, 098-0982915-2944]
- French National Research Agency [ANR-08-BLAN-0158-01, NT05-1-44224]
- Triangle de la Physique'' Foundation [2008-053T-SERPEBIO, 2010-003T-COMOVA]
- Agence Nationale de la Recherche (ANR) [ANR-08-BLAN-0158] Funding Source: Agence Nationale de la Recherche (ANR)
A conformation-selective photophysics study in phenylalanine model peptides, combining pump-probe gas phase experiments and excited state calculations, highlights for the first time the quenching properties of a primary amide group (through its n pi* excited state) along with the effect of vibrational energy that facilitates access to the conical intersection area.
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