期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 14, 期 4, 页码 1371-1380出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cp22937k
关键词
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资金
- United Kingdom Defence Science and Technology Laboratories [DSTLX1000054680]
- Israel Science Foundation [1109/09]
A theoretical model is described for the voltage-dependent capacitance across the interface between two immiscible electrolytic solutions that is partially or completely covered with nanoparticles. The model is based on the description of competitive contributions of electrical double layers at the free interface and around nanoparticles. The effect of different system parameters is rationalised, and theoretical predictions are shown to be in agreement with available experimental data. The model provides a route for the characterisation of nanoparticle layers at liquid/liquid interfaces using capacitance measurements.
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