期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 14, 期 27, 页码 9578-9581出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cp41012e
关键词
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资金
- NSERC
- NRC
- CIHR
- University of Saskatchewan
Comprehensive X-ray absorption near-edge structure spectroscopy at the C, O and Li K-edges and the Mn, Fe, and P L-edges of LiMn0.75Fe0.25PO4 nanorods-graphene has been reported in great detail. Compared to that of free standing graphene and LiMn0.75Fe0.25PO4, the intimate interaction between the nanorods and graphene via charge redistribution has been unambiguously confirmed. This interaction not only anchors the nanorods onto the graphene but also modifies its surface chemistry, both of which afford the nanorods-graphene hybrid an ultra-high rate performance in lithium ion batteries. Such knowledge is important for the understanding of hybrid nanomaterials for lithium ion batteries and allows rational design for further improvements in performance.
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