期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 13, 期 1, 页码 291-295出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c000961j
关键词
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资金
- National Research Foundation of Korea [2009-0079060]
- CNRS
- Universite Paris Sud 11
The photofragmentation by UV excitation of selectively prepared 1(+) and 3(+) tautomers of protonated adenine is studied after excitation at a 266 and 263 nm wavelengths with two different experimental set-ups located in Seoul and Orsay. While the production of 1(+) tautomers with an electrospray ion source is now well accepted, calculations were used to ascribe the preparation of 3(+) tautomers from cold adenine dimers. The fragmentation patterns are rather similar for both tautomers, suggesting similar mechanisms as a statistical fragmentation in the ground electronic state after internal conversion.
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