期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 12, 期 32, 页码 9188-9196出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cp00209g
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资金
- NIST [PMG 60NANB7D6153]
- Polish Ministry of Science and Higher Education [N N204 015338]
The dissociation energies of all rotation-vibrational states of the molecular HD in the ground electronic state are calculated to a high accuracy by including nonadiabatic, relativistic alpha(2), and quantum electrodynamic alpha(3) effects, with approximate treatment of small higher order alpha(4), and finite nuclear size corrections. The obtained result for the ground molecular state of 36 405.7828(10) cm(-1) is in a small disagreement with the latest most precise experimental value.
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