4.6 Article

Identification of the nitrogen species on N-doped graphene layers and Pt/NG composite catalyst for direct methanol fuel cell

期刊

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 12, 期 38, 页码 12055-12059

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cp00789g

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资金

  1. National Natural Science Foundation of China [NSFC 50725207, 20821003]
  2. National Basic Research Program of China [MOST 2007CB936400, 2009CB930400]
  3. Chinese Academy of Sciences

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Heat treatment of graphene oxide (GO) with ammonia flow at various temperatures resulted in different distribution of nitrogen species. Synchrotron based X-ray absorption near-edge structure (XANES) spectroscopy provides unambiguous evidence for the presence of three nitrogen species. The Pt/NG-800 composite exhibits outstanding electrocatalytic activity for methanol oxidation.

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