期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 12, 期 17, 页码 4295-4300出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b918587a
关键词
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资金
- Office of Naval Research [N000140510711]
- UMD-NSF-MRSEC [DMR 05-20471]
- Korean government (MEST) [R31-2008-000-10071-0]
Heterogeneous films of ordered CeO2/Ni concentric nanostructures have been fabricated through template-assisted electrodeposition. The free-standing films of Ni metal (8 mu m thickness) contain ordered arrays of ceria tubes (200 nm OD, 100 nm ID). Ni/CeO2 coaxial nanotubes were also obtained by tuning experimental conditions. The interfacial contact area within the 3-dimensional oxide nanotube/nickel matrix is similar to 100 times greater than 2-dimensional thin films of nickel and ceria of the same area. The use of the film as an anode electrocatalyst/current collector is demonstrated in a solid oxide fuel cell.
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