期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 12, 期 15, 页码 3878-3886出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b922867e
关键词
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资金
- Department of Science and Technology (DST)
- BRNS (DAE)
- CSIR
The effect of a polymer, polyethylene glycol with a molecular weight of 400 (PEG-400), on the dynamics of solvent and rotational relaxation have been investigated in [bmim][BF4]/TX100/cyclohexane microemulsions using steady state and time resolved fluorescence spectroscopy as a tool and coumarin 480 (C-480) as a fluorescence probe. The size of the microemulsions increases with addition of PEG-400, which was revealed by dynamic light scattering (DLS) measurement. This leads to faster collective motion of the cations and anions of [bmim][BF4], which contributes to faster solvent relaxation in microemulsions.
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