期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 11, 期 47, 页码 11134-11139出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b916591f
关键词
-
资金
- State Key Laboratory of Fine Chemicals [KF0609]
- Dalian University of Technology
- Education Ministry
- National Natural Science Foundation of China [20071108, 707016, 20872012, 20706008, 20725621]
- Education Department of Liaoning Province [2008S040]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0711]
- Specialized Research Fund for the Doctoral Program of Higher Education [200801411004]
N-(4-Hydroxy-phenoxyethyl)-N'-ethyl-4,4'-bipyridium (1) can form a stable 1 : 1 inclusion complex with CB[8] in aqueous solution, in which the hydroxyphenol (HP) moiety is back-folded and inserted together with the viologen moiety into the cavity of CB[8]. When the ethyl viologen dication (EV2+) in 1 is reduced, chemically or electrochemically, an intramolecular partner radical (EV+center dot-HP)/CB[8] can be detected, meanwhile, a dynamic balance between the partner radical and the intermolecular radical dimer (EV+center dot-HP)(2)/CB[8] can be observed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据