期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 10, 期 39, 页码 5957-5962出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b804800b
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资金
- Natural Sciences and Engineering Research Council of Canada
- NSERC Discovery
- TRIUMF by the National Research Council of Canada
- Mount Allison Majorie Young Bell Faculty Fellowship
- The New Brunswick Innovation Foundation
- Canada Research Chairs Program
- Canadian Foundation for Innovation
- Nova Scotia Research and Innovation Trust
- TRIUMF Centre for Molecular and Materials Science
- TRIUMF
The formation of the cyclohexadienyl radical, C(6)H(6)Mu, in ionic and molecular solvents has been compared. This is the first time that a muoniated free radical is reported in an ionic liquid. In marked contrast to molecular liquids, free radical generation in ionic liquids is significantly enhanced. Comparison of the hyper-fine interactions in the ionic liquid and in molecular solvents and with theoretical calculations, suggests significant and unforeseen solvent interaction with the cyclohexadienyl radical.
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