Cu2Zn1-xCdxSn(Se1-ySy)(4) solid solutions as absorber materials for solar cells

Cu2Zn1-xCdxSn(Se1-ySy)(4) monograin powders with different x- and y-values were prepared from binary compounds in the liquid phase of flux material (KI) in evacuated quartz ampoules. All the materials had uniform composition and p-type conductivity. PL spectra (10 K) of the as grown Cu2Zn1-xCdxSn(Se)(4) monograin powders showed one PL band with peak position around 0.85 eV which shifted linearly to the lower energy side with increasing Cd content. Cu2ZnSnS4 material showed asymmetrical PL band at 1.31 eV attributed to band-to-tail recombination. RT Raman spectra of Cu2ZnSnSe4 revealed two main peaks 196 cm(-1) and 173 cm(-1) and a third less intensive peak with varying peak position in the region 231 -253 cm(-1). Raman spectra of Cu2ZnSnS4 showed an intensive peak at 338 cm(-1) and additional peaks at 287 cm(-1) and 368 cm(-1). Narrow sieved fractions of grown powders were used as absorber materials in monograin layer (MGL) solar cell structures: graphite/Cu2Zn1-xCdxSn(Se1-ySy)(4)/CdS/ZnO. The best so far solar cell that was based on the Cu2Zn0.8Cd0.2SnSe4 had open circuit voltage 422 mV, short circuit current 12 mA/cm(2) and fill factor 44%.