Study of cerium doped magnetite (Fe3O4:Ce)/PMMA nanocomposites

The paper presents the synthesis and properties of polymer nanocomposite material based on cerium doped magnetite (Fe3O4) as filler material and poly methyl methacrylate (PMMA) as host matrix. The magnetite (Fe3O4) particles were synthesized by co-precipitation route using stable ferrous and ferric salts with ammonium hydroxide as precipitating agent. Further, they doped by cerium oxide (CeO2) non-stoichiometrically. The composite material was fabricated by solvent evaporation method. Here 2.4 GHz microwaves were used to study the effect of microwaves heating on polymerization. The phase and crystal structure is determined by X-ray diffraction (XRD). The average crystallite size of the composites varies from 28 to 35 nm. The chemical structure is confirmed by Fourier transform infrared (FTIR) spectroscopy. The magnetic and thermal properties are investigated by vibrating sample magnetometer (VSM) and differential scanning calorimetry (DSC). The thermal study shows that the microwave heated samples possess higher glass transition temperature (T-g). The magnetic results suggest that coercivity (H-c) and squareness (M-r/M-s) of the loop increases with increasing doping percent of cerium. (C) 2011 Elsevier B.V. All rights reserved.