期刊
PHYSICA B-CONDENSED MATTER
卷 405, 期 20, 页码 4386-4388出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.physb.2010.08.001
关键词
Crystal structure and symmetry; Phase transition; High pressure
High-pressure Raman spectroscopy and X-ray diffraction studies of celestite (SrSO(4)) were carried out in a diamond anvil cell at room temperature. Variation in the Raman vibrational frequency and change of lattice parameters with pressure indicate that a transformation occurs in celestite. This transformation caused an adjustment in the Sr-O polyhedra that affected the stretching-force constant of SO(4). Moreover, compressibilities along the crystallographic axes decreased in the order a to c to b. From the compression data, the bulk modulus of the celestite was 87 GPa. Both X-ray and Raman data show that the transition in celestite is reversible. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.
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