期刊
PHOTOCHEMISTRY AND PHOTOBIOLOGY
卷 87, 期 1, 页码 51-55出版社
WILEY
DOI: 10.1111/j.1751-1097.2010.00833.x
关键词
-
资金
- Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET) [PIP 6301/05]
- Agencia de Promocion Cientifica y Tecnologica (ANPCyT) [PICT 06-12610, PICT 33919]
- Universidad Nacional de La Plata (UNLP)
- Ministerio de Ciencia, Tecnologia e Innovacion Productiva (MinCyT, Argentina)
- ECOS-Sud (France) [A07E07]
7,8-Dihydroneopterin (H(2)Nep) is secreted during the oxidative burst of stimulated macrophages. The photochemistry of H(2)Nep was investigated in neutral aqueous solutions exposed to UV-A radiation (320-400 nm) at room temperature. The kinetics were followed by UV/Vis spectrophotometry and HPLC, whereas the photoproducts were analyzed by electrospray ionization mass spectrometry. Excitation of H(2)Nep leads to the formation of isomeric dimers with molecular masses equal to exactly twice the molecular mass of the reactant. The corresponding quantum yield of H(2)Nep consumption (Phi(-R) = (3.8 +/- 0.5) x 10(-2)) was independent of O-2 and reactant concentrations. Mechanistic implications are discussed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据