期刊
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
卷 10, 期 9, 页码 1415-1419出版社
SPRINGERNATURE
DOI: 10.1039/c1pp05055a
关键词
-
资金
- Korean Ministry of Education, Science and Technology [R31-2008-000-10059-0]
A new photo-switchable on-off host-guest system comprising cucurbit[7]uril (CB[7]) and a photoresponsive cinnamamide derivative (trans-(3-phenyl-acryloylamino)-acetic acid, E-1) is studied. The cinnamamide derivative and CB[7] forms a stable 1 : 1 host-guest complex (CB[7].E-1) with a high binding constant (K = 2.1 10(4) M-1). Irradiation of UV light (300 nm) to an aqueous solution of CB[7].E-1 induces the E-to Z-conformational change of the cinnamamide derivative, which then leads to the dissociation of the complex as evidenced by UV-visible and H-1-NMR spectroscopy. The reverse process, photo-induced host-guest complex formation between CB[7] and Z-1 is achieved by irradiation of UV light at 254 nm. The photo-switchable on-off host-guest system shows high reversibility and switching efficiency, which makes it potentially useful in designing photoresponsive gating systems.
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