期刊
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
卷 9, 期 8, 页码 1079-1081出版社
SPRINGERNATURE
DOI: 10.1039/c0pp00083c
关键词
-
资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [19050008]
Three dithienylethene derivatives having anthracene substituents (connected at 1-, 2- and 9-positions) were prepared. Although these three derivatives exhibit photochromic reactivity in solution, only one of the derivatives (connected at 2-position) undergoes the photochromic reaction in the crystalline phase. X-Ray crystallographic analysis and DFT calculation revealed that conformation of the anthracene substituents plays an important role in the crystalline photochromism.
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