期刊
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
卷 8, 期 8, 页码 1139-1149出版社
SPRINGERNATURE
DOI: 10.1039/b822173a
关键词
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资金
- Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET-PIP) [02470/00, 6301/05, 5443/05]
- Agencia de Promocion Cientifica y Tecnologica (ANPCyT) [PICT 06-12610, 06-0615, 33919]
- Universidad de Buenos Aires (UBA) [X072]
- The Matsumae International Foundation (MIF)
The photochemistry of norharmane (9H-pyrido[3,4-b]indole) in acidic (pH 5.0 +/- 0.1) and alkaline (pH 10.0 +/- 0.1) aqueous solutions was studied. The photochemical reactions were monitored by TLC, UV/VIS absorption spectroscopy, high-performance liquid chromatography ( HPLC), electronic ionization-mass spectrometry (EI-MS), UV-laser desorption/ionization-time of flight-mass spectrometry (UV-LDI-TOF-MS) and an enzymatic method for H2O2 determination. The neutral (nHoN) and the protonated (nHoH(+)) forms of norharmane irradiated under Ar atmosphere were photostable, but they suffered a photochemical transformation in the presence of O-2, yielding as photoproducts norharmane dimers, trimers and tetramers. nHoN shown to be more photostable than nHoH+. The nHoH+ and nHoN consumption quantum yields were 1.82 x 10(-3) and 0.51 x 10(-3), respectively, and the mechanisms involved in its photochemistry are discussed. H2O2 and singlet oxygen (O-1(2)) were also detected and quantified in irradiated solutions of norharmane, and their role in the photochemistry of norharmane is discussed.
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