期刊
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
卷 7, 期 12, 页码 1473-1479出版社
SPRINGERNATURE
DOI: 10.1039/b814230k
关键词
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资金
- Division Of Chemistry [0748525] Funding Source: National Science Foundation
Coumarin derivatives with non-polar substituents at the 6 or 7 position undergoes photodimerization in the presence of CB[ 8] in water to give the syn dimer as the major product. It is postulated that these neutral coumarins form dynamic complexes in the presence of CB[ 8] and the product selectivity is reflective of the type of complex, available volume in the CB[ 8] cavity and relative rate of photodimerization inside and outside the CB[ 8] cavity.
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