4.1 Article

Synthesis, Crystal Structure, and Properties of a Dinuclear Cu(I) Cluster

期刊

出版社

TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2013.765875

关键词

Dinuclear copper(I) cluster; supramolecular; substituent of triarylphosphine ligand; luminescence

资金

  1. National Natural Science Foundation of China [61205184, 11175169]
  2. Foundation of State Key Laboratory of Structural Chemistry [20110011]
  3. Natural Science Foundation of Zhejiang Province [Y4100610, LY12E02010]

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A new dinuclear copper(I) cluster complex, [(o-Tol)(3)PCuI2CuP(o-Tol)(3)(DMF)] (1) ((o-Tol)(3)P = tris(2- methylphenyl)phosphine, DMF = N, N-dimethylformamide), has been synthesized and the crystal structure was determined by a single-crystal X-ray diffraction study. The dinuclear copper(I) cluster molecule containing an asymmetric Cu2I2P2O core and the dinuclear clusters are fused together by a strong - stacking interaction to form asupramolecular one-dimensional (1D) chain. After having compared the relevant complexes composed of CuI and monodentate triarylphosphine ligands, the impact of the substituent of the triarylphosphine ligand to the subsequent complex structure has also been discussed.Except for a strong -* bond, the complex 1 also exhibits a weak metal-to-ligand charge transfer (MLCT) absorption bond in the 430-530-nm region and displays a weak green-yellow emission when irradiated by ultraviolet (UV) light. The thermogravimetric analysis demonstrates that its thermal stability is good, and the corresponding PXRD analysis has revealed that the final, organic-free decomposed product is CuI.

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