期刊
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
卷 185, 期 10, 页码 2064-2075出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426500903496705
关键词
Chemical warfare agents; Chemical Weapons Convention; DCC-Celite; nerve agents; phosphonates
This article describes rapid and efficient surface mediated synthesis of O-alkyl 2-methoxyethyl alkylphosphonates from alkylphosphonic acids and alcohols using dicyclohexyl carbodiimide (DCC)-Celite as a solid support. These compounds are markers of nerve agents. 2-Methoxyethyl methylphosphonic acids (2a-d) were reacted with various alcohols to yield O-alkyl 2-methoxyethyl alkylphosphonates (AMEAPs, 3a-m). This synthetic method has advantages over other methods in terms of selectivity, shorter reaction time, high yield, and easy work-up.
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