期刊
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
卷 185, 期 3, 页码 509-515出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426500902839830
关键词
Air; disulfides; Mn(III); oxidation; Schiff-base complex; thiols
资金
- Yasouj University, Yasouj, Iran
Bis(2-hydroxybenzene)phthaldiimine (BHBPDI) as a new quadridentate Schiff base ligand and its [Mn(III)(BHBPDI)Cl] complex were synthesized and characterized by analytical and spectral data (MS, FT-IR, UV-Vis, 1H NMR). The aerobic oxidation of thiols catalyzed by Mn(III)-complex using molecular oxygen was studied at room temperature. The reaction proceeded to yield the corresponding symmetric disulfides in good to high yields. The reaction was retarded when the reaction mixture was saturated with nitrogen gas. This system provides an efficient and convenient method for the oxidation of thiols to symmetric disulfides.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据