4.5 Review

Metal clusters inside out

出版社

ROYAL SOC
DOI: 10.1098/rsta.2009.0271

关键词

clusters; condensed clusters; suboxides; subnitrides; hydride halides; rare earths

向作者/读者索取更多资源

Solid-state chemistry of cluster compounds with metals in the left part of the periodic table is described. As a function of the metal valence electron concentration (VEC), characteristic changes occur with stepwise changing features. Strongly metal-metal-bonded and ligand-encapsulated clusters exist for large values of VEC. At decreased values, endohedral atoms stabilize the clusters, and with the lowest values, only clusters exist with no ligand shell. This general trend holds for systems with discrete, as well as condensed, clusters as illustrated for d metals, including the lanthanides, alkaline earth and alkali metals.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据