期刊
PHILOSOPHICAL MAGAZINE
卷 89, 期 10, 页码 907-923出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/14786430902814029
关键词
diffusion; thermal diffusion; Soret effect
类别
资金
- Deutsche Forschungsgemeinschaft (DFG) [Ko 1541/5-2]
We have measured the Soret (ST), diffusion (D), and thermal diffusion (DT) coefficients of three binary mixtures of dodecane (DD), isobutylbenzene (IB) and 1,2,3,4-tetrahydronaphthalene (TH) for a concentration of 50 wt% at a temperature of 25C by means of an optical beam deflection cell. This relevant experimental technique was still missing from a recent benchmark campaign for the measurement of the Soret effect. The measured coefficients agree to within a few percent (10% for ST, D of TH/IB) with the proposed benchmark values. A detailed analysis of the measurement process of the beam deflection cell, which allows for an elegant extension to include temperature gradients within the windows, is given, and improved benchmark values are suggested. In addition, ethanol-water mixtures have been investigated very carefully over a broad concentration and temperature range. Comparison with data of Kolodner and Wiegand gives a generally good agreement with some systematic deviations. Contrary to theoretical predictions, we have not been able to identify a second sign change of ST at high ethanol concentrations.
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