期刊
PHILOSOPHICAL MAGAZINE
卷 88, 期 33-35, 页码 4197-4203出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/14786430802484881
关键词
glass transition; specific heat; Brillouin scattering; orientationally-disordered crystals; ethanol; crystallization kinetics
Calorimetric and acoustic experiments were conducted on pure ethanol in the temperature range around 80-180 K, in which different solid-solid and solid-liquid transitions are observed. Using a versatile calorimetric experimental system, the specific heats of the different phases were accurately measured and the phase transitions between them investigated. The latter investigation was supported by complementary Brillouin-scattering experiments. The influence of several factors in the kinetics of crystallization versus vitrification is demonstrated and briefly discussed.
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