期刊
PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION
卷 30, 期 6, 页码 557-564出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ppsc.201300020
关键词
nanocarbon; fluorescent nanodots; electrocatalysis; oxygen reduction reactions
资金
- NRF from MEST, Republic of Korea [2010-0029128]
- National Research Foundation of Korea [2010-0029128] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Metal-free nitrogen and phosphorus dual-doped, electrocatlytically active, functionalized nanocarbon (FNC) and photoluminescent carbon nanodots (PCNDs) are simultaneously synthesized using a facile one-pot microwave-assisted process. The successful incorporation of phosphorus and nitrogen to oxygen rich PCNDs and FNC are confirmed using surface morphological and spectral studies. The characterization studies of FNC further reveals the presence of edge-plane-like sites/defects and remarkable electrocatalytical activity. In addition to the electroctalytical activity, FNC shows attractive properties as a metal-free oxygen reduction catalyst and is resistant to methanol crossover effects in alkaline media. The 5-10 nm PCNDs, which exhibit blue fluorescence under UV exposure, are successfully used for bioimaging applications.
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