期刊
ORGANOMETALLICS
卷 37, 期 19, 页码 3286-3297出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00470
关键词
-
资金
- National Science Foundation [CHE-1362501, CHE-1726308]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1362501] Funding Source: National Science Foundation
A series of six pincer ruthenium complexes has been synthesized and applied in the catalytic hydrogenation of esters. The ruthenium complexes have the formula Ru(pincer)HCl(CO), where the CNN-pincer ligands feature N-heterocyclic carbene (NHC), pyridine, and dialkylamino donor groups. Through systematic variation of the steric bulk of the NHC substituent and the amine substituents, a clear structure function relationship emerges. The most active catalysts in this series feature the bulkiest NHC substituent employed, 2,6-diisopropylphenyl. For the dialkylamino group, catalysts substituted with isopropyl or ethyl groups were the most active, while catalysts substituted with methyl groups were significantly less active. The most active catalyst discovered catalyzes the complete hydrogenation of a range of esters at loadings of 0.05-0.2 mol %.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据