期刊
ORGANOMETALLICS
卷 37, 期 17, 页码 2837-2841出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00549
关键词
-
资金
- Zhejiang Natural Science Fund for Young Scholars [LQ18B020008]
- Zhejiang Sci-Tech University [17062078-Y]
A gold-catalyzed regiospecific hydration of N-tosyl propargylic amines has been developed. In the presence of a catalytic amount of the gold catalyst NaAuCl4 center dot 2H(2)O, both alkyl and aryl-substituted N-tosyl propargylic amines were smoothly converted into the corresponding beta-amino ketones with excellent regioselectivities and high yields (up to 85%). Further transformations of the obtained beta-amino ketones to valuable 1,3-amino alcohols were demonstrated as well.
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