期刊
ORGANOMETALLICS
卷 34, 期 11, 页码 2098-2101出版社
AMER CHEMICAL SOC
DOI: 10.1021/om501165z
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资金
- ERC [338944 - GOCAT]
- Leverhulme Trust
- Johnson Matthey PLC
- University of East Anglia
Dioxygen reacts with the gold(I) hydride (IPr)AuH under insertion to give the hydroperoxide AuOOH, a long-postulated reaction in gold catalysis and the first demonstration of O-2 activation by Au-H in a well-defined system. Subsequent condensation gave the peroxide (IPr)Au-OO-Au(IPr),(IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol=2-ylidene). The reaction kinetics are reported, as well as the reactivity of Au(I) hydrides with radical scavengers.
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