期刊
ORGANOMETALLICS
卷 33, 期 23, 页码 6868-6878出版社
AMER CHEMICAL SOC
DOI: 10.1021/om500933w
关键词
-
资金
- European Research Council (ERC-StG ISORI) [258299]
- European Union [226716]
- European Research Council (ERC) [258299] Funding Source: European Research Council (ERC)
Investigation of catalytic organometallic reactions often relies on mass spectrometry. Frequently, however, possible reaction intermediates along the catalytic cycle correspond to the same mass-to-charge ratio and have rather similar molecular composition. We have shown for the CC coupling between phenylacetylene and pyridine catalyzed by the ruthenium complex [RuCp(PPh3)(Py)(2)](+) that using a combination of collision-induced dissociation experiments, infrared multiphoton dissociation spectroscopy, bimolecular reactions, and DFT calculations it is possible to study isobaric complexes and characterize the key intermediates in the reaction cycle. In addition, a so far elusive ruthenium complex with p-coordinated alkyne molecule has been spectroscopically characterized.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据