期刊
ORGANOMETALLICS
卷 33, 期 9, 页码 2247-2256出版社
AMER CHEMICAL SOC
DOI: 10.1021/om5001293
关键词
-
资金
- National Research Foundation (NRF)
- DST-NRF Centre of Excellence in Catalysis (c*change)
- Erasmus Mundus EUROSA program
A series of novel neutral and cationic methylpalladium complexes bearing N-alkyl-2,2'-dipyridylaldiminato ligands were prepared and characterized. In the presence of ethylene, the cationic complexes were active as dimerization catalysts, producing a mixture of 1- and 2-butenes. A Pd-ethyl pi-ethylene species was identified as the catalyst resting state by low-temperature spectroscopic and DFT studies, which provided insights into the effect of both steric and electronic factors on the observed reactivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据