期刊
ORGANOMETALLICS
卷 34, 期 1, 页码 78-85出版社
AMER CHEMICAL SOC
DOI: 10.1021/om500884b
关键词
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资金
- NSF [CHE-9208463, CHE-9629688, CHE-9974839]
- National Science Foundation [CHE-0840494]
Cyclotetrasiloxanes 13 containing different silole-based fluorogenic units (silafluorene, 1,3-diphenyl-9-silafluorene, tetraphenylsilole) were synthesized by cohydrolysis and condensation reactions. Their optical properties in solution and as crystals were studied. These compounds have low quantum yields in solution (Phi(fl) = 0.01-0.18) with fluorescence maxima at 359-375 nm for silafluorene-containing compounds 1 and 3 and at 491 nm for AEE-active tetraphenylsilole compound 2. However, 13 have high solid-state quantum yields (Phi(fl) = 0.65-0.78) with fluorescence maxima at 377-390 nm for compounds 1 and 3 and at 517 nm for tetraphenylsilole- and silafluorene-containing compound 2. Packing analysis of 13 in the crystal structure and MO and excited-state calculations were performed to explore possible fluorescence mechanisms in these compounds.
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